Reflectance

Spectral reflectance curves for aluminium (Al), silver (Ag), and gold (Au) metal mirrors at normal incidence.

Reflectance of the surface of a material is its effectiveness in reflecting radiant energy. It is the fraction of incident electromagnetic power that is reflected at an interface. The reflectance spectrum or spectral reflectance curve is the plot of the reflectance as a function of wavelength.

Mathematical definitions

Hemispherical reflectance

The hemispherical reflectance of a surface, denoted R, is defined as

$R={\frac {\Phi _{\mathrm {e} }^{\mathrm {r} }}{\Phi _{\mathrm {e} }^{\mathrm {i} }}},$

where

• Φ_e^r is the radiant flux reflected by that surface;
• Φ_eⁱ is the radiant flux received by that surface.

Spectral hemispherical reflectance

The spectral hemispherical reflectance in frequency and spectral hemispherical reflectance in wavelength of a surface, denoted R_ν and R_λ respectively, are defined as

$R_{\nu }={\frac {\Phi _{\mathrm {e} ,\nu }^{\mathrm {r} }}{\Phi _{\mathrm {e} ,\nu }^{\mathrm {i} }}},$

$R_{\lambda }={\frac {\Phi _{\mathrm {e} ,\lambda }^{\mathrm {r} }}{\Phi _{\mathrm {e} ,\lambda }^{\mathrm {i} }}},$

where

• Φ_e,ν^r is the spectral radiant flux in frequency reflected by that surface;
• Φ_e,νⁱ is the spectral radiant flux in frequency received by that surface;
• Φ_e,λ^r is the spectral radiant flux in wavelength reflected by that surface;
• Φ_e,λⁱ is the spectral radiant flux in wavelength received by that surface.

Directional reflectance

The directional reflectance of a surface, denoted R_Ω, is defined as

$R_{\Omega }={\frac {L_{\mathrm {e} ,\Omega }^{\mathrm {r} }}{L_{\mathrm {e} ,\Omega }^{\mathrm {i} }}},$

where

• L_e,Ω^r is the radiance reflected by that surface;
• L_e,Ωⁱ is the radiance received by that surface.

Spectral directional reflectance

The spectral directional reflectance in frequency and spectral directional reflectance in wavelength of a surface, denoted R_Ω,ν and R_Ω,λ respectively, are defined as

$R_{\Omega ,\nu }={\frac {L_{\mathrm {e} ,\Omega ,\nu }^{\mathrm {r} }}{L_{\mathrm {e} ,\Omega ,\nu }^{\mathrm {i} }}},$

$R_{\Omega ,\lambda }={\frac {L_{\mathrm {e} ,\Omega ,\lambda }^{\mathrm {r} }}{L_{\mathrm {e} ,\Omega ,\lambda }^{\mathrm {i} }}},$

where

• L_e,Ω,ν^r is the spectral radiance in frequency reflected by that surface;
• L_e,Ω,νⁱ is the spectral radiance received by that surface;
• L_e,Ω,λ^r is the spectral radiance in wavelength reflected by that surface;
• L_e,Ω,λⁱ is the spectral radiance in wavelength received by that surface.

Reflectivity

Fresnel reflection coefficients for a boundary surface between air and a variable material in dependence of the complex refractive index and the angle of incidence.

"Reflectivity" redirects here. For the EM formulation, see Fresnel power reflection.

For homogeneous and semi-infinite (see halfspace) materials, reflectivity is the same as reflectance. Reflectivity is the square of the magnitude of the Fresnel reflection coefficient, which is the ratio of the reflected to incident electric field; as such the reflection coefficient can be expressed as a complex number as determined by the Fresnel equations for a single layer, whereas the reflectance is always a positive real number.

For layered and finite media, according to the CIE, reflectivity is distinguished from reflectance by the fact that reflectivity is a value that applies to thick reflecting objects. When reflection occurs from thin layers of material, internal reflection effects can cause the reflectance to vary with surface thickness. Reflectivity is the limit value of reflectance as the sample becomes thick; it is the intrinsic reflectance of the surface, hence irrespective of other parameters such as the reflectance of the rear surface. Another way to interpret this is that the reflectance is the fraction of electromagnetic power reflected from a specific sample, while reflectivity is a property of the material itself, which would be measured on a perfect machine if the material filled half of all space.

Surface type

Given that reflectance is a directional property, most surfaces can be divided into those that give specular reflection and those that give diffuse reflection:

• for specular surfaces, such as glass or polished metal, reflectance will be nearly zero at all angles except at the appropriate reflected angle; that is, reflected radiation will follow a different path from incident radiation for all cases other than radiation normal to the surface;
• for diffuse surfaces, such as matte white paint, reflectance is uniform; radiation is reflected in all angles equally or near-equally. Such surfaces are said to be Lambertian.

Most real objects have some mixture of diffuse and specular reflective properties.

Water reflectance

Reflectance of smooth water at 20°C (refractive index 1.333).

Reflection occurs when light moves from a medium with one index of refraction into a second medium with a different index of refraction.

Specular reflection from a body of water is calculated by the Fresnel equations. Fresnel reflection is directional and therefore does not contribute significantly to albedo which primarily diffuses reflection.

A real water surface may be wavy. Reflectance, which assumes a flat surface as given by the Fresnel equations, can be adjusted to account for waviness.

Grating efficiency

The generalization of reflectance to a diffraction grating, which disperses light by wavelength, is called diffraction efficiency.

SI radiometry units

SI radiometry units

Quantity		Unit		Dimension	Notes
Name	Symbol	Name	Symbol	Symbol
Radiant energy	Qe	joule	J	M⋅L2⋅T−2	Energy of electromagnetic radiation.
Radiant energy density	we	joule per cubic metre	J/m3	M⋅L−1⋅T−2	Radiant energy per unit volume.
Radiant flux	Φe	watt	W = J/s	M⋅L2⋅T−3	Radiant energy emitted, reflected, transmitted or received, per unit time. This is sometimes also called "radiant power".
Spectral flux	Φe,ν	watt per hertz	W/Hz	M⋅L2⋅T−2	Radiant flux per unit frequency or wavelength. The latter is commonly measured in W⋅nm−1.
	Φe,λ	watt per metre	W/m	M⋅L⋅T−3
Radiant intensity	Ie,Ω	watt per steradian	W/sr	M⋅L2⋅T−3	Radiant flux emitted, reflected, transmitted or received, per unit solid angle. This is a directional quantity.
Spectral intensity	Ie,Ω,ν	watt per steradian per hertz	W⋅sr−1⋅Hz−1	M⋅L2⋅T−2	Radiant intensity per unit frequency or wavelength. The latter is commonly measured in W⋅sr−1⋅nm−1. This is a directional quantity.
	Ie,Ω,λ	watt per steradian per metre	W⋅sr−1⋅m−1	M⋅L⋅T−3
Radiance	Le,Ω	watt per steradian per square metre	W⋅sr−1⋅m−2	M⋅T−3	Radiant flux emitted, reflected, transmitted or received by a surface, per unit solid angle per unit projected area. This is a directional quantity. This is sometimes also confusingly called "intensity".
Spectral radiance	Le,Ω,ν	watt per steradian per square metre per hertz	W⋅sr−1⋅m−2⋅Hz−1	M⋅T−2	Radiance of a surface per unit frequency or wavelength. The latter is commonly measured in W⋅sr−1⋅m−2⋅nm−1. This is a directional quantity. This is sometimes also confusingly called "spectral intensity".
	Le,Ω,λ	watt per steradian per square metre, per metre	W⋅sr−1⋅m−3	M⋅L−1⋅T−3
Irradiance Flux density	Ee	watt per square metre	W/m2	M⋅T−3	Radiant flux received by a surface per unit area. This is sometimes also confusingly called "intensity".
Spectral irradiance Spectral flux density	Ee,ν	watt per square metre per hertz	W⋅m−2⋅Hz−1	M⋅T−2	Irradiance of a surface per unit frequency or wavelength. This is sometimes also confusingly called "spectral intensity". Non-SI units of spectral flux density include jansky (1 Jy = 10−26 W⋅m−2⋅Hz−1) and solar flux unit (1 sfu = 10−22 W⋅m−2⋅Hz−1 = 104 Jy).
	Ee,λ	watt per square metre, per metre	W/m3	M⋅L−1⋅T−3
Radiosity	Je	watt per square metre	W/m2	M⋅T−3	Radiant flux leaving (emitted, reflected and transmitted by) a surface per unit area. This is sometimes also confusingly called "intensity".
Spectral radiosity	Je,ν	watt per square metre per hertz	W⋅m−2⋅Hz−1	M⋅T−2	Radiosity of a surface per unit frequency or wavelength. The latter is commonly measured in W⋅m−2⋅nm−1. This is sometimes also confusingly called "spectral intensity".
	Je,λ	watt per square metre, per metre	W/m3	M⋅L−1⋅T−3
Radiant exitance	Me	watt per square metre	W/m2	M⋅T−3	Radiant flux emitted by a surface per unit area. This is the emitted component of radiosity. "Radiant emittance" is an old term for this quantity. This is sometimes also confusingly called "intensity".
Spectral exitance	Me,ν	watt per square metre per hertz	W⋅m−2⋅Hz−1	M⋅T−2	Radiant exitance of a surface per unit frequency or wavelength. The latter is commonly measured in W⋅m−2⋅nm−1. "Spectral emittance" is an old term for this quantity. This is sometimes also confusingly called "spectral intensity".
	Me,λ	watt per square metre, per metre	W/m3	M⋅L−1⋅T−3
Radiant exposure	He	joule per square metre	J/m2	M⋅T−2	Radiant energy received by a surface per unit area, or equivalently irradiance of a surface integrated over time of irradiation. This is sometimes also called "radiant fluence".
Spectral exposure	He,ν	joule per square metre per hertz	J⋅m−2⋅Hz−1	M⋅T−1	Radiant exposure of a surface per unit frequency or wavelength. The latter is commonly measured in J⋅m−2⋅nm−1. This is sometimes also called "spectral fluence".
	He,λ	joule per square metre, per metre	J/m3	M⋅L−1⋅T−2
Hemispherical emissivity	ε	N/A		1	Radiant exitance of a surface, divided by that of a black body at the same temperature as that surface.
Spectral hemispherical emissivity	εν  or ελ	N/A		1	Spectral exitance of a surface, divided by that of a black body at the same temperature as that surface.
Directional emissivity	εΩ	N/A		1	Radiance emitted by a surface, divided by that emitted by a black body at the same temperature as that surface.
Spectral directional emissivity	εΩ,ν  or εΩ,λ	N/A		1	Spectral radiance emitted by a surface, divided by that of a black body at the same temperature as that surface.
Hemispherical absorptance	A	N/A		1	Radiant flux absorbed by a surface, divided by that received by that surface. This should not be confused with "absorbance".
Spectral hemispherical absorptance	Aν  or Aλ	N/A		1	Spectral flux absorbed by a surface, divided by that received by that surface. This should not be confused with "spectral absorbance".
Directional absorptance	AΩ	N/A		1	Radiance absorbed by a surface, divided by the radiance incident onto that surface. This should not be confused with "absorbance".
Spectral directional absorptance	AΩ,ν  or AΩ,λ	N/A		1	Spectral radiance absorbed by a surface, divided by the spectral radiance incident onto that surface. This should not be confused with "spectral absorbance".
Hemispherical reflectance	R	N/A		1	Radiant flux reflected by a surface, divided by that received by that surface.
Spectral hemispherical reflectance	Rν  or Rλ	N/A		1	Spectral flux reflected by a surface, divided by that received by that surface.
Directional reflectance	RΩ	N/A		1	Radiance reflected by a surface, divided by that received by that surface.
Spectral directional reflectance	RΩ,ν  or RΩ,λ	N/A		1	Spectral radiance reflected by a surface, divided by that received by that surface.
Hemispherical transmittance	T	N/A		1	Radiant flux transmitted by a surface, divided by that received by that surface.
Spectral hemispherical transmittance	Tν  or Tλ	N/A		1	Spectral flux transmitted by a surface, divided by that received by that surface.
Directional transmittance	TΩ	N/A		1	Radiance transmitted by a surface, divided by that received by that surface.
Spectral directional transmittance	TΩ,ν  or TΩ,λ	N/A		1	Spectral radiance transmitted by a surface, divided by that received by that surface.
Hemispherical attenuation coefficient	μ	reciprocal metre	m−1	L−1	Radiant flux absorbed and scattered by a volume per unit length, divided by that received by that volume.
Spectral hemispherical attenuation coefficient	μν  or μλ	reciprocal metre	m−1	L−1	Spectral radiant flux absorbed and scattered by a volume per unit length, divided by that received by that volume.
Directional attenuation coefficient	μΩ	reciprocal metre	m−1	L−1	Radiance absorbed and scattered by a volume per unit length, divided by that received by that volume.
Spectral directional attenuation coefficient	μΩ,ν  or μΩ,λ	reciprocal metre	m−1	L−1	Spectral radiance absorbed and scattered by a volume per unit length, divided by that received by that volume.
See also: SI · Radiometry · Photometry

See also

• Bidirectional reflectance distribution function
• Emissivity
• Lambert's cosine law
• Transmittance
• Sun path
• Light Reflectance Value
• Albedo

External links

• Reflectivity of metals (chart).
• Reflectance Data.